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Dialdehyde cellulose nanocrystal cross-linked chitosan foam with high adsorption capacity for removal

《化学科学与工程前沿（英文）》 2023年 第17卷 第7期   页码 853-866 doi: 10.1007/s11705-022-2256-x

摘要： The discharge of large amounts of dye-containing wastewater seriously threats the environment. Adsorbents have been adopted to remove these dyes present in the wastewater. However, the high adsorption capacity, predominant pH-responsibility, and excellent recyclability are three challenges to the development of efficient adsorbents. The poly(acryloxyethyl trimethylammonium chloride)-graft-dialdehyde cellulose nanocrystals were synthesized in our work. Subsequently, the cationic dialdehyde cellulose nanocrystal cross-linked chitosan nanocomposite foam was fabricated via freeze-drying of the hydrogel. Under the optimal ratio of the cationic dialdehyde cellulose nanocrystal/chitosan (w/w) of 12/100, the resultant foam (Foam-12) possesses excellent absorption properties, such as high porosity, high content of active sites, strong acid resistance, and high amorphous region. Then, Foam-12 was applied as an eco-friendly adsorbent to remove acid red 134 (a representative of anionic dyes) from aqueous solutions. The maximum dye adsorption capacity of 1238.1 mg∙g‒1 is achieved under the conditions of 20 mg∙L‒1 adsorbents, 100 mg∙L‒1 dye, pH 3.5, 24 h, and 25 °C. The dominant adsorption mechanism for the anionic dye adsorption is electrostatic attraction, and Foam-12 can effectively adsorb acid red 134 at pH 2.5–5.5 and be desorbed at pH 8. Its easy recovery and good reusability are verified by the repeated acid adsorption–alkaline desorption experiments.

关键词： chitosan foam     cellulose nanocrystals     acid red 134     adsorption    

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Promoting hydrogen industry with high-capacity Mg-based solid-state hydrogen storage materials and systems

《能源前沿（英文）》 2023年 第17卷 第3期   页码 320-323 doi: 10.1007/s11708-023-0889-1

摘要： Promoting hydrogen industry with high-capacity Mg-based solid-state hydrogen storage materials and systems

关键词： materials systems    

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Calculation of diagonal section and cross-section bending capacity for strengthening RC structure usinghigh-performance ferrocement laminate

Shouping SHANG , Fangyuan ZHOU , Wei LIU ,

《结构与土木工程前沿（英文）》 2009年 第3卷 第3期   页码 330-338 doi: 10.1007/s11709-009-0046-x

摘要： Because there is a great demand of reinforcement and retrofitting of aged structures nationwide, as well as the rapid development of innovative building materials, the adoption of strengthening RC structures using new inorganic materials has become possible. High-performance ferrocement laminate (HPFL) is an effective method of strengthening concrete structure. High-performance ferrocement laminate is a new type of inorganic material with the advantages such as high strength, small contraction, good bonding properties, etc. This paper introduces the formula of cross-section bending capacity for strengthening concrete beams with HPEL. A comparative analysis of experimental data, as well as the calculation of diagonal section bearing capacity of concrete members, is given.

关键词： RC beams     high-performance ferrocement laminate (HPFL)     inorganic material     reinforcement    

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of biomass-derived carbon loaded with MnO as lithium-ion battery anode for improving its reversible capacity

《化学科学与工程前沿（英文）》 2023年 第18卷 第1期 doi: 10.1007/s11705-023-2376-y

摘要： Biomass-derived carbon materials for lithium-ion batteries emerge as one of the most promising anodes from sustainable perspective. However, improving the reversible capacity and cycling performance remains a long-standing challenge. By combining the benefits of K2CO3 activation and KMnO4 hydrothermal treatment, this work proposes a two-step activation method to load MnO2 charge transfer onto biomass-derived carbon (KAC@MnO2). Comprehensive analysis reveals that KAC@MnO2 has a micro-mesoporous coexistence structure and uniform surface distribution of MnO2, thus providing an improved electrochemical performance. Specifically, KAC@MnO2 exhibits an initial charge-discharge capacity of 847.3/1813.2 mAh·g–1 at 0.2 A·g–1, which is significantly higher than that of direct pyrolysis carbon and K2CO3 activated carbon, respectively. Furthermore, the KAC@MnO2 maintains a reversible capacity of 652.6 mAh·g–1 after 100 cycles. Even at a high current density of 1.0 A·g–1, KAC@MnO2 still exhibits excellent long-term cycling stability and maintains a stable reversible capacity of 306.7 mAh·g–1 after 500 cycles. Compared with reported biochar anode materials, the KAC@MnO2 prepared in this work shows superior reversible capacity and cycling performance. Additionally, the Li+ insertion and de-insertion mechanisms are verified by ex situ X-ray diffraction analysis during the charge-discharge process, helping us better understand the energy storage mechanism of KAC@MnO2.

关键词： biomass-derived carbon     MnO2     lithium-ion batteries     anode material     high reversible capacity    

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Fabrication of high-capacity cation-exchangers for protein adsorption: Comparison of grafting-from and

Ming Zhao, Run Liu, Jian Luo, Yan Sun, Qinghong Shi

《化学科学与工程前沿（英文）》 2019年 第13卷 第1期   页码 120-132 doi: 10.1007/s11705-018-1730-y

摘要： In this work, we have synthesized two polymer-grafted cation exchangers: one via the grafting-from approach, in which sulfopropyl methacrylate (SPM) is grafted through atom transfer radical polymerization onto Sepharose FF (the thus resulting exchanger is referred as Sep- -SPM), and another via the grafting-to approach, in which the polymer of SPM is directly coupled onto Sepharose FF (the thus resulting exchanger is called as Sep- SPM). Protein adsorption on these two cation exchangers have been also investigated. At the same ligand density, Sep- -SPM has a larger accessible pore radius and a smaller depth of polymer layer than Sep- SPM, due to the controllable introduction of polymer chains with the regular distribution of the ligand. Therefore, high-capacity adsorption of lysozyme and -globulin could be achieved simultaneously in Sep- -SPM with an ionic capacity (IC) of 308 mmol·L . However, Sep- SPM has an irregular chain distribution and different architecture of polymer layer, which lead to more serious repulsive interaction to proteins, and thus Sep- SPM has a lower adsorption capacity for -globulin than Sep- -SPM with the similar IC. Moreover, the results from protein uptake experiments indicate that the facilitated transport of adsorbed -globulin occurs only in Sep- SPM and depends on the architecture of polymer layers. Our research provides a clear clue for the development of high-performance protein chromatography.

关键词： polymer-grafted ionic exchanger     grafting technique     protein adsorption     atom transfer radical polymerization     γ-globulin    

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Kombucha SCOBY-based carbon and graphene oxide wrapped sulfur/polyacrylonitrile as a high-capacity cathode

Krishnaveni Kalaiappan, Subadevi Rengapillai, Sivakumar Marimuthu, Raja Murugan, Premkumar Thiru

《化学科学与工程前沿（英文）》 2020年 第14卷 第6期   页码 976-987 doi: 10.1007/s11705-019-1897-x

摘要： Hierarchically-porous carbon nano sheets were prepared as a conductive additive for sulfur/polyacrylonitrile (S/PAN) composite cathodes using a simple heat treatment. In this study, kombucha (that was derived from symbiotic culture of bacteria and yeast) carbon (KC) and graphene oxide (GO) were used as a carbon host matrix. These rational-designed S/PAN/KC/GO hybrid composites greatly suppress the diffusion of polysulfides by providing strong physical and chemical adsorption. The cathode delivered an initial discharge capacity of 1652 mAh·g at a 0.1 C rate and a 100 cycle capacity of 1193 mAh·g . The nano sheets with embedded hierarchical pores create a conductive network that provide effective electron transfer and fast electrochemical kinetics. Further, the nitrogen component of PAN can raise the affinity/interaction of the carbon host with lithium polysulfides, supporting the cyclic performance. The results exploit the cumulative contribution of both the conductive carbon matrix and PAN in the enhanced performance of the positive electrode.

关键词： sulfur cathode     kombucha SCOBY     graphene oxide     polyacrylonitrile     lithium-sulfur battery    

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Studying the stress-suction coupling in soils using an oedometer equipped with a high capacity tensiometer

Trung Tinh LE, Yu-Jun CUI, Juan Jorge MU?OZ, Pierre DELAGE, Anh Minh TANG, Xiang-Ling LI

《结构与土木工程前沿（英文）》 2011年 第5卷 第2期   页码 160-170 doi: 10.1007/s11709-011-0106-x

摘要： In the context of research into deep nuclear waste disposal, various works have concerned the hydromechanical behavior of Boom clay, a stiff plastic clay extracted in the SCK-CEN Underground Research Laboratory near the Mol City (Belgium), at a depth of 223 m. Due to some amount of smectite minerals in the clay fraction, Boom clay exhibits swelling properties when hydrated under low stresses. To investigate some aspects of the hydromechanical behavior of Boom clay, oedometer compression tests were carried out on samples of Boom clay close to saturation and submitted to an initial suction. During oedometer compression, the changes in suction with increased vertical stress are monitored by means of a high capacity tensiometer installed at the bottom of the sample. Some aspects related to hydromechanical couplings are examined through the investigation of the changes in suction during oedometer compression, a somewhat delicate and poorly documented experimental approach. A comparison is also made with a completely different soil sample under suction, i.e. a statically compacted unsaturated low plasticity silt. Some technical difficulties typical of this new experimental approach are first described in detail so as to optimize the interpretation of the data obtained. The experiment allows the determination of the point at which suction is changed to positive pressure during compression. Below this point, the ratio between the vertical stress and the change in suction are determined. Above this point, the data show that positive pore pressures are dissipated in a common way. The suction/stress behavior during unloading is also described and discussed. Finally, an interpretation in terms of microstructure effects is provided for both samples. The experimental approach initiated here seems to provide interesting further application to better understand hydromechanical couplings in natural soils in relation with suction increase during stress release.

关键词： Oedometer     tensiometer     swelling     physicochemical and mechanical effects     stress/suction coupling     soil plasticity    

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oxide cathode with synergistic engineering of calcium-ion intercalation and polyaniline coating for high

《化学科学与工程前沿（英文）》 2023年 第17卷 第9期   页码 1244-1253 doi: 10.1007/s11705-022-2293-5

摘要： Vanadium oxides as cathode for zinc-ion batteries have attracted much attention because of their high theoretical capacity, flexible layered structure and abundant resources. However, cathodes are susceptible to the collapse of their layered structure and the dissolution of vanadium after repeated long cycles, which worsen their capacities and cycling stabilities. Herein, a synergistic engineering of calcium-ion intercalation and polyaniline coating was developed to achieve the superior electrochemical performance of vanadium pentoxide for zinc-ion batteries. The pre-intercalation of calcium-ion between vanadium pentoxide layers as pillars increase the crystal structure’s stability, while the polyaniline coating on the cathodes improves the conductivity and inhibits the dissolution of vanadium. This synergistic engineering enables that the battery system based-on the polyaniline coated calcium vanadate cathode to deliver a high capacity of 406.4 mAh·g−1 at 1 A·g−1, an ultralong cycle life over 6000 cycles at 10 A·g−1 with 93% capacity retention and high-rate capability. The vanadium oxide cathode with synergistic engineering of calcium-ion intercalation and polyaniline coating was verified to effectively improve the electrochemical performance of zinc-ion batteries.

关键词： zinc-ion battery     CaV8O20     polyaniline coating     synergistic engineering     high capacity     long durability    

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An approach for evaluating fire resistance of high strength Q460 steel columns

Wei-Yong WANG, Guo-Qiang LI, Bao-lin YU

《结构与土木工程前沿（英文）》 2014年 第8卷 第1期   页码 26-35 doi: 10.1007/s11709-014-0239-9

摘要： To develop a methodology for evaluating fire resistance of high strength Q460 steel columns, the load bearing capacity of high strength Q460 steel columns is investigated. The current approach of evaluating load bearing capacity of mild steel columns at room temperature is extended to high strength Q460 steel columns with due consideration to high temperature properties of high strength Q460 steel. The critical temperature of high strength Q460 steel column is presented and compared with mild steel columns. The proposed approach was validated by comparing the predicted load capacity with that evaluated through finite element analysis and test results. In addition, parametric studies were carried out by employing the proposed approach to study the effect of residual stress and geometrical imperfections. Results from parametric studies show that, only for a long column (slenderness higher than 75), the magnitude and distribution mode of residual stress have little influence on ultimate load bearing capacity of high strength Q460 steel columns, but the geometrical imperfections have significant influence on any columns. At a certain slenderness ratio, the stability factor first decreases and then increases with temperature rise.

关键词： high strength Q460 steel     load bearing capacity     temperature    

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Model test of the group piles foundation of a high-speed railway bridge in mined-out area

Xin LIANG,Qian-gong CHENG,Jiu-jiang WU,Jian-ming CHEN

《结构与土木工程前沿（英文）》 2016年 第10卷 第4期   页码 488-498 doi: 10.1007/s11709-016-0338-x

摘要： The research on the mechanism of pile-soil-cap-goaf interaction and settlement of high-speed railway bridge located in mined-out area is still relatively rare. By taking the pile group of Guanshandi bridge foundation in Hefei-Fuzhou high-speed railway as the prototype, a model test is carried out. According to the similarity theory, the similar constant is derived and the similar model material is determined. Meanwhile, three types of data including the bearing behavior of piles, and the settlement law, and soil among piles are investigated. It can be found that: the influence of goaf on the bearing capacity of pile is inversely to the loading degree, the larger of loading degree, the smaller impact of goaf on the bearing capacity. There is no negative side friction can been found in pile body and the degree of downward tendency for the barycenter of side friction layout is obvious for piles in goaf. Although the bearing ratio of soil resistance under cap is relatively large, the cap effect is suggested be ignored considering the characteristic of goaf. There is a maximum critical value for the uneven settlement of pile group in goaf, and when the value is reached, the uneven settlement stop growing anymore. In addition, the formula for calculating bearing capacity and settlement of pile group in goaf based on test results, theory analysis and related standard is established.

关键词： high-speed railway     mined-out areas     goaf     group piles foundation     physical model test     bearing capacity     settlement    

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基于自适应四叉树分块与最高有效位预测的大容量密文域可逆信息隐藏算法 Research Article

祁凯莉,张敏情,狄富强,孔咏骏

《信息与电子工程前沿（英文）》 2023年 第24卷 第8期   页码 1156-1168 doi: 10.1631/FITEE.2200501

摘要： 为提高密文域可逆信息隐藏（reversible data hiding in encrypted images，RDH-EI）算法的嵌入容量，提出一种基于自适应四叉树分块和最高有效位（most significant bit，MSB）预测的大容量RDH-EI方案。首先根据图像的平滑程度进行自适应四叉树分块，然后将不同大小的块进行块级加密和置乱，以抵抗对于加密图像的分析。在嵌入数据阶段，对于文献Wang & He（2022）提出的自适应MSB预测方法进行改进，以块中左上角像素为目标像素，用于预测其它像素，从而腾出更多嵌入空间。首次将四叉树分块方法应用于密文域图像的可逆信息隐藏。模拟结果表明，所提方法具有可逆性与可分离性，并且在自适应MSB预测方法基础上进一步提高了平均嵌入容量。对于512×512大小的灰度图像，平均嵌入容量提高约25 565比特，对于所有嵌入容量有所提高的较平滑图像，平均嵌入容量提高约35 530比特。

关键词： 自适应四叉树分块；自适应最高有效位预测；密文域可逆信息隐藏；高嵌入容量    

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Mechatronic design of a novel linear compliant positioning stage with large travel range and high out-of-planepayload capacity

Hua LIU, Xin XIE, Ruoyu TAN, Lianchao ZHANG, Dapeng FAN

《机械工程前沿（英文）》 2017年 第12卷 第2期   页码 265-278 doi: 10.1007/s11465-017-0453-y

摘要：

Most of the XY positioning stages proposed in previous studies are mainly designed by considering only a single performance indicator of the stage. As a result, the other performance indicators are relatively weak. In this study, a 2-degree-of-freedom linear compliant positioning stage (LCPS) is developed by mechatronic design to balance the interacting performance indicators and realize the desired positioning stage. The key parameters and the coupling of the structure and actuators are completely considered in the design. The LCPS consists of four voice coil motors (VCMs), which are conformally designed for compactness, and six spatial leaf spring parallelograms. These parallelograms are serially connected for a large travel range and a high out-of-plane payload capacity. The mechatronic model is established by matrix structural analysis for structural modeling and by Kirchhoff’s law for the VCMs. The sensitivities of the key parameters are analyzed, and the design parameters are subsequently determined. The analytical model of the stage is confirmed by experiments. The stage has a travel range of 4.4 mm× 7.0 mm and a 0.16% area ratio of workspace to the outer dimension of the stage. The values of these performance indicators are greater than those of any existing stage reported in the literature. The closed-loop bandwidth is 9.5 Hz in both working directions. The stage can track a circular trajectory with a radius of 1.5 mm, with 40 mm error and a resolution of lower than 3 mm. The results of payload tests indicate that the stage has at least 20 kg out-of-plane payload capacity.

关键词： mechatronic design     linear compliant positioning stage     large travel range     high out-of-plane payload capacity     spatial parallelogram     voice coil motor     sensitivity analysis    

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Efficient acetylene/carbon dioxide separation with excellent dynamic capacity and low regeneration energy

《化学科学与工程前沿（英文）》   页码 1616-1622 doi: 10.1007/s11705-022-2183-x

摘要： Adsorptive separation of acetylene/carbon dioxide mixtures by porous materials is an important and challenging task due to their similar sizes and physical properties. Here, remarkable acetylene/carbon dioxide separation featuring a high dynamic breakthrough capacity for acetylene (4.3 mmol·g–1) as well as an ultralow acetylene regeneration energy (29.5 kJ·mol–1) was achieved with the novel TiF62–-pillared material ZU-100 (TIFSIX-bpy-Ni). Construction of a pore structure with abundant TiF62– anion sites and pores with appropriate sizes enabled formation of acetylene clusters through hydrogen bonds and intermolecular interactions, which afforded a high acetylene capacity (8.3 mmol·g–1) and high acetylene/carbon dioxide uptake ratio (1.9) at 298 K and 1 bar. Moreover, the NbO52– anion-pillared material ZU-61 investigated for separation of acetylene/carbon dioxide. In addition, breakthrough experiments were also conducted to further confirm the excellent dynamic acetylene/carbon dioxide separation performance of ZU-100.

关键词： adsorption     acetylene/carbon dioxide separation     dynamic capacity     anion-pillared hybrid material    

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Buffer capacity of granular matter to impact of spherical projectile based on discrete element method

Ying YAN, Pengfei LI, Shunying JI

《结构与土木工程前沿（英文）》 2013年 第7卷 第1期   页码 50-54 doi: 10.1007/s11709-013-0186-x

摘要： Granular matter possesses impact-absorbing property due to its energy dissipation character. To investigate the impact-absorbing capacity of granular matter, the discrete element method (DEM) is adopted to simulate the impact of a spherical projectile on to a granular bed. The dynamic responses of the projectile are obtained for both thin and thick granular bed. The penetration depth of the projectile and the first impact peak are investigated with different bed thicknesses and impact velocities. Determining a suitable bed thickness is crucial to the buffering effect of granular matter. The first impact peak is independent of bed thickness when the thickness is larger than the critical thickness.

关键词： granular matter     impact peak     buffer capacity     discrete element method     critical thickness    

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Dynamic simulation of urban water metabolism under water environmental carrying capacity restrictions

Weihua ZENG,Bo WU,Ying CHAI

《环境科学与工程前沿（英文）》 2016年 第10卷 第1期   页码 114-128 doi: 10.1007/s11783-014-0669-6

摘要： A revised concept for urban water metabolism (UWM) is presented in this study to address the inadequacies in current research on UWM and the problems associated with the traditional urban water metabolic process. Feedback loops can be analyzed to increase the water environmental carrying capacity (WECC) of the new urban water metabolism system (UWMS) over that of a traditional UWMS. An analysis of the feedback loops of an UWMS was used to construct a system dynamics (SD) model for the system under a WECC restriction. Water metabolic processes were simulated for different scenarios using the Tongzhou District in Beijing as an example. The results for the newly developed UWM case showed that a water environment of Tongzhou District could support a population of 1.1926 × 10 , an irrigation area of 375.521 km , a livestock of 0.7732 × 10 , and an industrial value added of ¥193.14 × 10 (i.e. about US$28.285× 10 ) in 2020. A sensitivity analysis showed that the WECC could be improved to some extent by constructing new sewage treatment facilities or by expanding the current sewage treatment facilities, using reclaimed water and improving the water circulation system.

关键词： urban water metabolism system (UWMS)     system dynamic simulation     water environmental carrying capacity (WECC)     feedback loops     bilateral control    

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标题 作者 时间 类型 操作

Dialdehyde cellulose nanocrystal cross-linked chitosan foam with high adsorption capacity for removal

期刊论文

Promoting hydrogen industry with high-capacity Mg-based solid-state hydrogen storage materials and systems

期刊论文

Calculation of diagonal section and cross-section bending capacity for strengthening RC structure usinghigh-performance ferrocement laminate

Shouping SHANG , Fangyuan ZHOU , Wei LIU ,

期刊论文

of biomass-derived carbon loaded with MnO as lithium-ion battery anode for improving its reversible capacity

期刊论文

Fabrication of high-capacity cation-exchangers for protein adsorption: Comparison of grafting-from and

Ming Zhao, Run Liu, Jian Luo, Yan Sun, Qinghong Shi

期刊论文

Kombucha SCOBY-based carbon and graphene oxide wrapped sulfur/polyacrylonitrile as a high-capacity cathode

Krishnaveni Kalaiappan, Subadevi Rengapillai, Sivakumar Marimuthu, Raja Murugan, Premkumar Thiru

期刊论文

Studying the stress-suction coupling in soils using an oedometer equipped with a high capacity tensiometer

Trung Tinh LE, Yu-Jun CUI, Juan Jorge MU?OZ, Pierre DELAGE, Anh Minh TANG, Xiang-Ling LI

期刊论文

oxide cathode with synergistic engineering of calcium-ion intercalation and polyaniline coating for high

期刊论文

An approach for evaluating fire resistance of high strength Q460 steel columns

Wei-Yong WANG, Guo-Qiang LI, Bao-lin YU

期刊论文

Model test of the group piles foundation of a high-speed railway bridge in mined-out area

Xin LIANG,Qian-gong CHENG,Jiu-jiang WU,Jian-ming CHEN

期刊论文

基于自适应四叉树分块与最高有效位预测的大容量密文域可逆信息隐藏算法

祁凯莉,张敏情,狄富强,孔咏骏

期刊论文

Mechatronic design of a novel linear compliant positioning stage with large travel range and high out-of-planepayload capacity

Hua LIU, Xin XIE, Ruoyu TAN, Lianchao ZHANG, Dapeng FAN

期刊论文

Efficient acetylene/carbon dioxide separation with excellent dynamic capacity and low regeneration energy

期刊论文

Buffer capacity of granular matter to impact of spherical projectile based on discrete element method

Ying YAN, Pengfei LI, Shunying JI

期刊论文

Dynamic simulation of urban water metabolism under water environmental carrying capacity restrictions

Weihua ZENG,Bo WU,Ying CHAI

期刊论文